2e:["$","li","2",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":3}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"Here, acetylene reacts with sodium to produce sodium acetylide and hydrogen gas."}}]]}] 2f:["$","li","3",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":4}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"2. Acetylene reacts with ammoniacal silver nitrate :"}}]]}] 38:T121a,

\mathrm{CH} \equiv \mathrm{CH} + 2\mathrm{AgNO}_3 \longrightarrow \mathrm{Ag}_2\mathrm{C}_2 + 2\mathrm{HNO}_3

30:["$","li","4",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":5}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$38"}}]]}] 31:["$","li","5",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":6}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"In this reaction, acetylene reacts with ammoniacal silver nitrate to form a white precipitate of silver acetylide and nitric acid."}}]]}] 39:T475,3. Acetylene reaction with hydrochloric acid in the presence of a

\mathrm{Hg}^{2+}

catalyst (oxymercuration-demercuration) :32:["$","li","6",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":7}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$39"}}]]}] 3a:T1569,

\mathrm{CH} \equiv \mathrm{CH} + \mathrm{Hg(OAc)_2} + \mathrm{H}_2\mathrm{O} \longrightarrow \mathrm{CH}_2=\mathrm{CH}-\mathrm{OH} + \mathrm{HgOAc}

33:["$","li","7",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":8}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3a"}}]]}] 3b:T1890,

\mathrm{CH}_2=\mathrm{CH}-\mathrm{OH} + \mathrm{NaBH}_4 \longrightarrow \mathrm{CH}_2=\mathrm{CH}-\mathrm{H} + \mathrm{B(OH)_3} + \mathrm{NaOAc}

34:["$","li","8",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":9}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3b"}}]]}] 3c:Tda4,Acetylene does not readily react with

\mathrm{HCl}

. However, in the presence of a catalyst like

\mathrm{Hg}^{2+}

, a specific type of electrophilic addition known as oxymercuration can occur. The result is vinyl chloride. Note that

\mathrm{NaBH}_4

is used to reduce the mercurinium ion intermediate and to replace the

\mathrm{Hg}

group with a hydrogen atom.35:["$","li","9",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":10}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3c"}}]]}] 36:["$","li","10",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":11}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"4. Acetylene does not react with sodium hydroxide :"}}]]}] 3d:T73b,

\mathrm{CH} \equiv \mathrm{CH} + \mathrm{NaOH} \longrightarrow \text { no reaction }

37:["$","li","11",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":12}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3d"}}]]}]

More on Hydrocarbons

More on Hydrocarbons