39:T179b,

E = E^\circ + \frac{RT}{2F} \ln \left( \frac{[\mathrm{H^+}]^2}{P_{\mathrm{H_2}}} \right)

2e:["$","li","1",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":2}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$39"}}]]}] 2f:["$","li","2",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":3}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"where:"}}]]}] 30:["$","li","3",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":4}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"E is the electrode potential."}}]]}] 31:["$","li","4",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":5}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"E^∘ is the standard electrode potential, which is 0 V for the hydrogen electrode."}}]]}] 3a:T8a7,R is the gas constant,

8.314 \, \mathrm{J \cdot mol^{-1} \cdot K^{-1}}

.32:["$","li","5",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":6}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3a"}}]]}] 3b:T5c8,T is the temperature in Kelvin:

25^{\circ} \mathrm{C} = 298 \, \mathrm{K}

.33:["$","li","6",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":7}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3b"}}]]}] 3c:T5d7,F is the Faraday constant,

96485 \, \mathrm{C \cdot mol^{-1}}

.34:["$","li","7",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":8}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3c"}}]]}] 3d:T40d,

[\mathrm{H^+}]

is the concentration of hydrogen ions.35:["$","li","8",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":9}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3d"}}]]}] 3e:T6ab,

P_{\mathrm{H_2}}

is the pressure of hydrogen gas.36:["$","li","9",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":10}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3e"}}]]}] 3f:Tbd9,In pure water at

25^{\circ} \mathrm{C}

[\mathrm{H^+}] = 10^{-7} \, \mathrm{M}

. To make the emf zero, we set E to 0 in the Nernst equation:37:["$","li","10",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":11}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$3f"}}]]}] 40:T16ff,

0 = 0 + \frac{8.314 \times 298}{2 \times 96485} \ln \left( \frac{(10^{-7})^2}{P_{\mathrm{H_2}}} \right)

38:["$","li","11",{"className":"flex items-start gap-3","children":[["$","span",null,{"className":"mt-0.5 flex h-5 w-5 shrink-0 items-center justify-center rounded-md bg-surface-sunken font-mono text-[11px] text-ink-400","children":12}],["$","div",null,{"className":"min-w-0 max-w-[68ch] flex-1 text-[15px] leading-relaxed text-ink-600 [&_.katex-display]:my-3 [&_.katex-display]:overflow-x-auto","dangerouslySetInnerHTML":{"__html":"$40"}}]]}]

More on Electrochemistry

More on Electrochemistry